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chemistry at the University of Edinburgh
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Our research group uses a combination of field measurements, laboratory experiments and modelling to investigate some of the fluxes and chemical processes that occur within the lower atmosphere and the impacts of these on the terrestrial environment and on human health. Current areas of research, most in collaboration, include:
- Characterization of airborne particulate matter from different microenvironments
of exposure to determine the sources and chemical evolution of atmospheric
particles, and for application to epidemiological studies and biological
toxicity assays
- Particulate matter and NO2 measurement method validation and intercomparison,
and the modelling of small-scale spatial and temporal variations in
urban air pollution for estimating human exposure
- High resolution modelling of atmospheric chemistry, with particular
focus on ozone and particulate matter
- Measurement of the magnitude and controlling factors on methyl bromide
emission fluxes from terrestrial systems such as salt marshes, woodland
soils and decaying leaf and woody litter
- Measurement of the concentrations and emission fluxes of volatile
organic compounds (natural and anthropogenic) using gas chromatography
and proton transfer reaction-mass spectrometry combined with eddy covariance
- Speciation of organic nitrogen compounds in rainwater and in the gas-phase,
and the relationship with dissolved and gaseous inorganic nitrogen
- Quantification of the kinetics of gas-to-liquid transfer of aromatic
VOC into aqueous solution
SELECTED RECENT PUBLICATIONS
- Drewer, J., Heal, K.V., Smith, K. and Heal, M.R. (2008) Methyl bromide
fluxes to the atmosphere from temperate woodland ecosystems. Global
Change Biology 14, 2539-2547, doi:10.1111/j.1365-2486.2008.01676.x
- Heal, M.R. (2008) The effect of absorbent preparation method on precision
and accuracy of ambient nitrogen dioxide measurement by Palmes passive
diffusion tube. J. Environ. Monitor. 10, 1363-1369, doi:10.1039/b811230d
- Heal, M.R., Harrison, M.A.J. and Cape, J.N. (2007) Aqueous-phase nitration
of phenol by N2O5 and ClNO2. Atmos.
Environ. 41, 3515-3520.
- Freney, E.J., Heal, M.R., Donovan, R.J., et al. (2006) A single-particle
characterization of a mobile Versatile Aerosol Concentration Enrichment
System for exposure studies, Particle & Fibre Toxicology
3:8.
- Drewer, J., Heal, M.R., Heal, K.V. and Smith, K. (2006) Temporal and
spatial variation in methyl bromide emissions from a salt marsh. Geophys.
Res. Letts. 33, L16808, doi:10.1029/2006GL026814.
- Heal, M.R., Hibbs, L.R., Agius, R.M. and Beverland, I.J. (2005) Total
and water soluble trace metal content of urban background PM10,
PM2.5 and Black Smoke in Edinburgh, UK, Atmos. Environ.
39, 1417-1430.
- Heal, M.R., Hibbs, L.R., Agius, R.M. and Beverland, I.J. (2005) Interpretation
of variations in fine, coarse and black smoke particulate matter concentrations
in a Northern European city. Atmos. Environ. 39, 3711-3718.
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